Radical coupling or oxidation of the titanium(III)dimethyl precursor (PNP)Ti(CH3)2 produced the dimethyl compounds, (PNP)Ti(CH3)2(X) (X = TEMPO, OMes*, OTf), which then thermally extrude methane to cyclometallate (X = TEMPO) or form the methylidene (X = OMes* or OTf). Various NMR spectral experiments in addition to 13C isotopic labeling, and structural studies are reported.
T. Kurogi, P. J. Carroll and D. J. Mindiola, Chem. Commun., 2017, 53, 3412 DOI: 10.1039/C7CC00371D
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