Issue 22, 2017

Dynamic behaviours of a rationally prepared flexible MOF by postsynthetic modification of ligand struts

Abstract

Through postsynthetic modification of ligand struts, controllable conversion of a Zr MOF between rigidity and flexibility is realized. The rationally prepared flexible MOF exhibits interesting dynamic behaviours, such as reversible structural deformation, vapour sorption hysteresis and unexpected adsorption of bulky guest molecules.

Graphical abstract: Dynamic behaviours of a rationally prepared flexible MOF by postsynthetic modification of ligand struts

Supplementary files

Article information

Article type
Communication
Submitted
10 Jan 2017
Accepted
23 Feb 2017
First published
23 Feb 2017

Chem. Commun., 2017,53, 3220-3223

Dynamic behaviours of a rationally prepared flexible MOF by postsynthetic modification of ligand struts

X. Xu, F. Yang, S. Chen, J. He, Y. Xu and W. Wei, Chem. Commun., 2017, 53, 3220 DOI: 10.1039/C7CC00230K

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