We demonstrate the evaporation rate-based selection of supramolecular chirality for the first time. P-type aggregates prepared by fast evaporation, and M-type aggregates prepared by slow evaporation are kinetic and thermodynamic products under dynamic reaction conditions, respectively. These findings provide a novel solution reaction chemistry under the dynamic reaction conditions.
S. Hattori, S. Vandendriessche, G. Koeckelberghs, T. Verbiest and K. Ishii, Chem. Commun., 2017, 53, 3066 DOI: 10.1039/C6CC09842H
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