Issue 18, 2017
From the journal:

Chemical Communications

Selective hydrogenolysis of carbon–oxygen bonds with formic acid over a Au–Pt alloy catalyst†

Liang Wang,*a   Jian Zhang,a   Guoxiong Wang,a   Wei Zhang, ORCID logo *b   Chengtao Wang,a   Chaoqun Biana  and  Feng-Shou Xiao ORCID logo *ac  

* Corresponding authors

a Key Laboratory of Applied Chemistry of Zhejiang Province, Department of Chemistry, Zhejiang University, Hangzhou 310028, China
E-mail: liangwang@zju.edu.cn, fsxiao@zju.edu.cn

b Department of Materials Science and Key Laboratory of Mobile Materials MOE, Jilin University, Changchun 130012, China
E-mail: weizhang@jlu.edu.cn

c Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Zhejiang University, Hangzhou 310027, China

Abstract

We reported selective hydrogenolysis of carbon–oxygen species over a CeO2-supported Au–Pt alloy catalyst (Au–Pt/CeO2) using biomass-derived formic acid as the hydrogen source. The success of this reaction is reasonably attributed to the high efficiency of Au–Pt/CeO2 in the tandem steps of formic acid dehydrogenation and carbon–oxygen species hydrodeoxygenation.

Graphical abstract: Selective hydrogenolysis of carbon–oxygen bonds with formic acid over a Au–Pt alloy catalyst

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Article information

DOI
https://doi.org/10.1039/C6CC09599B
Article type
Communication
Submitted
02 Dec 2016
Accepted
06 Feb 2017
First published
07 Feb 2017

Chem. Commun., 2017,53, 2681-2684

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Selective hydrogenolysis of carbon–oxygen bonds with formic acid over a Au–Pt alloy catalyst

L. Wang, J. Zhang, G. Wang, W. Zhang, C. Wang, C. Bian and F. Xiao, Chem. Commun., 2017, 53, 2681 DOI: 10.1039/C6CC09599B

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