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Issue 6, 2017
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Bis(amidinate) ligands in early lanthanide chemistry – synthesis, structures, and hydroamination catalysis

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Abstract

Bis(amidinate) ligands attached to rigid dibenzofuran and phenanthrene backbones have been introduced into lanthanide chemistry for the first time. Depending on the ligand and on the lanthanide source, either bi- and tetra-metallic macrocycles or monometallic complexes were obtained. The mono- and bi-metallic systems were compared in terms of their reactivity in the intramolecular hydroamination reaction. Depending on the catalyst used (mono vs. bimetallic) different rate laws were observed.

Graphical abstract: Bis(amidinate) ligands in early lanthanide chemistry – synthesis, structures, and hydroamination catalysis

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Article information


Submitted
09 Nov 2016
Accepted
19 Dec 2016
First published
03 Jan 2017

Chem. Commun., 2017,53, 1060-1063
Article type
Communication

Bis(amidinate) ligands in early lanthanide chemistry – synthesis, structures, and hydroamination catalysis

N. Kazeminejad, D. Munzel, M. T. Gamer and P. W. Roesky, Chem. Commun., 2017, 53, 1060
DOI: 10.1039/C6CC08958E

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