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Issue 1, 2017
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Dynamic covalent single chain nanoparticles based on hetero Diels–Alder chemistry

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Abstract

We introduce the fully reversible folding of single chain nanoparticles (SCNPs) based on covalent hetero Diels–Alder (HDA) chemistry. A cyclopentadiene (Cp)-protected cyanodithioester (CDTE) monomer is designed and copolymerized with methyl methacrylate (MMA) via RAFT polymerization. The polymer chains are folded and subsequently unfolded by exploiting the reversible nature of the HDA reaction.

Graphical abstract: Dynamic covalent single chain nanoparticles based on hetero Diels–Alder chemistry

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Article information


Submitted
11 Sep 2016
Accepted
08 Nov 2016
First published
15 Nov 2016

Chem. Commun., 2017,53, 157-160
Article type
Communication

Dynamic covalent single chain nanoparticles based on hetero Diels–Alder chemistry

N. Wedler-Jasinski, T. Lueckerath, H. Mutlu, A. S. Goldmann, A. Walther, M. H. Stenzel and C. Barner-Kowollik, Chem. Commun., 2017, 53, 157
DOI: 10.1039/C6CC07427H

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