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Issue 5, 2017
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Cyclotrimerisation of isocyanates catalysed by low-coordinate Mn(ii) and Fe(ii) m-terphenyl complexes

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Abstract

Two- and three-coordinate m-terphenyl complexes of manganese and iron are efficient catalysts for the selective cyclotrimerisation of primary aliphatic isocyanates affording isocyanurates in short reaction times and under mild conditions.

Graphical abstract: Cyclotrimerisation of isocyanates catalysed by low-coordinate Mn(ii) and Fe(ii) m-terphenyl complexes

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Supplementary files

Article information


Submitted
05 Sep 2016
Accepted
16 Dec 2016
First published
16 Dec 2016

Chem. Commun., 2017,53, 937-940
Article type
Communication

Cyclotrimerisation of isocyanates catalysed by low-coordinate Mn(II) and Fe(II) m-terphenyl complexes

H. R. Sharpe, A. M. Geer, H. E. L. Williams, T. J. Blundell, W. Lewis, A. J. Blake and D. L. Kays, Chem. Commun., 2017, 53, 937
DOI: 10.1039/C6CC07243G

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