Jump to main content
Jump to site search

Issue 5, 2017
Previous Article Next Article

New insights into the microstructure of translucent CaAlSiN3:Eu2+ phosphor ceramics for solid-state laser lighting

Author affiliations

Abstract

Newly emerged phosphor ceramics play key roles in high-brightness solid-state laser lighting technologies. Recently, we developed a translucent CaAlSiN3:Eu2+ red-emitting ceramic, with high quantum efficiency (up to 60%) and thermal robustness (15% higher than the powders). In the current work, detailed structural analyses are carried out by advanced analytical techniques, such as TEM and EPMA, in tandem with the CL, to reveal the correlation between the optical properties and the microstructure, especially the contribution of the interface. It was found that the ceramics consist of many core–shell structured phosphor particles. The shell is coated by a highly crystallized Ca-α-Sialon thin layer to reduce the surface defects. Such core–shell particles are embedded in a non-luminescent matrix of nano-sized Ca-α-Sialon particles tightly surrounded by an amorphous phase, both of which have little influence on the light propagation. Thanks to the unique core–shell structure of phosphor particles and the tight interfaces in the matrix, the bulk CaAlSiN3:Eu2+ ceramic shows record high performance under blue laser irradiation. The output luminous flux increases linearly as the incident power density increases from 20 to 150 W cm−2 with a constant high luminous efficacy of 42.2 lm W−1, demonstrating its promising application in solid-state laser lighting.

Graphical abstract: New insights into the microstructure of translucent CaAlSiN3:Eu2+ phosphor ceramics for solid-state laser lighting

Back to tab navigation

Publication details

The article was received on 16 Nov 2016, accepted on 25 Dec 2016 and first published on 28 Dec 2016


Article type: Paper
DOI: 10.1039/C6TC04987G
J. Mater. Chem. C, 2017,5, 1042-1051

  •   Request permissions

    New insights into the microstructure of translucent CaAlSiN3:Eu2+ phosphor ceramics for solid-state laser lighting

    S. Li, D. Tang, Z. Tian, X. Liu, T. Takeda, N. Hirosaki, F. Xu, Z. Huang and R. Xie, J. Mater. Chem. C, 2017, 5, 1042
    DOI: 10.1039/C6TC04987G

Search articles by author

Spotlight

Advertisements