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Issue 27, 2017
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Structural and electrochemical studies of novel Na7V3Al(P2O7)4(PO4) and Na7V2Al2(P2O7)4(PO4) high-voltage cathode materials for Na-ion batteries

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Abstract

A series of Na7V4−x3+Alx(P2O7)4(PO4) (x = 0, 1, 2, and 4) materials were synthesized by flux crystal growth. Novel Na7V4−xAlx(P2O7)4(PO4) (x = 1 and 2) compositions were structurally characterized by single crystal and powder X-ray diffraction analyses using laboratory and high-resolution synchrotron X-ray sources. The investigation of the electrochemical behavior of two new mixed V/Al phases as positive electrodes in Na-based batteries was performed using charge–discharge galvanostatic tests and operando X-ray diffraction experiments. It is demonstrated that the substitution of a part of vanadium with aluminum in Na7V4(P2O7)4(PO4) significantly increases the gravimetric capacity of these materials: from 70.9 mA h g−1 to 113.1 mA h g−1 and from 48.1 mA h g−1 to 92.7 mA h g−1 in Na7V3Al(P2O7)4(PO4) and Na7V2A2l(P2O7)4(PO4), respectively thanks to the activation of the V4+/V5+ redox couple. Different degrees of reversibility of the electrochemical reactions operating on the V3+/V4+ and V4+/V5+ redox couples in Na7V3Al(P2O7)4(PO4) are discussed from the analysis of operando X-ray diffraction.

Graphical abstract: Structural and electrochemical studies of novel Na7V3Al(P2O7)4(PO4) and Na7V2Al2(P2O7)4(PO4) high-voltage cathode materials for Na-ion batteries

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Supplementary files

Article information


Submitted
28 Apr 2017
Accepted
07 Jun 2017
First published
09 Jun 2017

J. Mater. Chem. A, 2017,5, 14365-14376
Article type
Paper

Structural and electrochemical studies of novel Na7V3Al(P2O7)4(PO4) and Na7V2Al2(P2O7)4(PO4) high-voltage cathode materials for Na-ion batteries

V. M. Kovrugin, J. Chotard, F. Fauth, A. Jamali, R. David and C. Masquelier, J. Mater. Chem. A, 2017, 5, 14365
DOI: 10.1039/C7TA03687F

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