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Issue 44, 2017
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Coating of Pd/C catalysts with Lewis-acidic ionic liquids and liquid coordination complexes – SCILL induced activity enhancement in arene hydrogenation

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Abstract

New solid catalysts with ionic liquid layer (SCILLs) were prepared by the coating of heterogeneous Pd/C catalysts with a thin film of acidic liquid: a known chloroaluminate ionic liquid (IL), [BMIM]Cl/AlCl3, and a recently developed liquid coordination complex (LCC), urea/AlCl3. Both coatings improved the activity of Pd/C catalyst against toluene hydrogenation; at lower temperatures (40 °C) the IL-SCILL performed better, whereas at 80 °C the LCC-SCILL gave higher conversion. A thin film of ionic liquid proved to be sufficient to increase activity, while larger volumes of ionic liquid resulted in a decrease in activity due to pore blocking and hence mass transport limitations. Kinetic investigations in batch mode revealed a zero order with respect to toluene concentration, a first order in hydrogen pressure, and activation energy of 64.7 kJ mol−1 for the Pd/C catalyst. The SCILL catalysts had slightly lower values of 53.1 kJ mol−1 for [BMIM]Cl/AlCl3 and 61.4 kJ mol−1 for urea/AlCl3, respectively.

Graphical abstract: Coating of Pd/C catalysts with Lewis-acidic ionic liquids and liquid coordination complexes – SCILL induced activity enhancement in arene hydrogenation

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Supplementary files

Article information


Submitted
21 Mar 2017
Accepted
12 May 2017
First published
23 May 2017

This article is Open Access

RSC Adv., 2017,7, 27558-27563
Article type
Paper

Coating of Pd/C catalysts with Lewis-acidic ionic liquids and liquid coordination complexes – SCILL induced activity enhancement in arene hydrogenation

M. Lijewski, J. M. Hogg, M. Swadźba-Kwaśny, P. Wasserscheid and M. Haumann, RSC Adv., 2017, 7, 27558
DOI: 10.1039/C7RA03295A

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