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Issue 34, 2017
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7-Step total synthesis of (+)-EBC-329: Photoisomerisation reveals new seco-casbane family member

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Abstract

The first seco-casbane, EBC-329, isolated from the Australian rainforest, was synthesised from (+)-2-carene in seven steps. This endeavour not only established the absolute stereochemical assignment as (8R,9S)-EBC-329, but also identified, via photoisomerisation, a new seco-casbane family member.

Graphical abstract: 7-Step total synthesis of (+)-EBC-329: Photoisomerisation reveals new seco-casbane family member

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Article information


Submitted
09 Jun 2017
Accepted
07 Aug 2017
First published
18 Aug 2017

Org. Biomol. Chem., 2017,15, 7102-7105
Article type
Communication

7-Step total synthesis of (+)-EBC-329: Photoisomerisation reveals new seco-casbane family member

T. J. Vanden Berg, D. M. Pinkerton and C. M. Williams, Org. Biomol. Chem., 2017, 15, 7102
DOI: 10.1039/C7OB01400G

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