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Issue 30, 2017
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Spacer type mediated tunable spin crossover (SCO) characteristics of pyrene decorated 2,6-bis(pyrazol-1-yl)pyridine (bpp) based Fe(ii) molecular spintronic modules

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Abstract

A simple “isomer-like” variation of the spacer group in a set of Fe(II) spin crossover (SCO) complexes designed to probe spin state dependence of electrical conductivity in graphene-based molecular spintronic junctions led to the observation of remarkable variations in the thermal- and light-induced magnetic characteristics, paving a simple route for the design of functional SCO complexes with different temperature switching regimes based on a 2,6-bis(pyrazol-1-yl)pyridine ligand skeleton.

Graphical abstract: Spacer type mediated tunable spin crossover (SCO) characteristics of pyrene decorated 2,6-bis(pyrazol-1-yl)pyridine (bpp) based Fe(ii) molecular spintronic modules

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Supplementary files

Article information


Submitted
19 Jun 2017
Accepted
03 Jul 2017
First published
03 Jul 2017

Dalton Trans., 2017,46, 9765-9768
Article type
Communication

Spacer type mediated tunable spin crossover (SCO) characteristics of pyrene decorated 2,6-bis(pyrazol-1-yl)pyridine (bpp) based Fe(II) molecular spintronic modules

K. S. Kumar, I. Šalitroš, E. Moreno-Pineda and M. Ruben, Dalton Trans., 2017, 46, 9765
DOI: 10.1039/C7DT02219K

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