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Issue 23, 2017
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Bicyclo[2.2.2]octane-1,4-dicarboxylic acid: towards transparent metal–organic frameworks

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Abstract

The preparation of transparent porous materials can offer a different access towards the study of molecules under solid confined space. Metal–organic frameworks represent a unique opportunity due to their tunable pore size, however aromatic linkers present strong absorption and reduce the transparency. Herein, we report the first example of a MOF with bicyclic organic dicarboxylic linkers and its use as a solid solvent.

Graphical abstract: Bicyclo[2.2.2]octane-1,4-dicarboxylic acid: towards transparent metal–organic frameworks

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Article information


Submitted
09 Mar 2017
Accepted
10 May 2017
First published
10 May 2017

Dalton Trans., 2017,46, 7397-7402
Article type
Communication

Bicyclo[2.2.2]octane-1,4-dicarboxylic acid: towards transparent metal–organic frameworks

P. J. Llabres-Campaner, J. Pitarch-Jarque, R. Ballesteros-Garrido, B. Abarca, R. Ballesteros and E. García-España, Dalton Trans., 2017, 46, 7397
DOI: 10.1039/C7DT00855D

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