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Issue 11, 2017
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Highly efficient cold-white light emission in a [Au2CuCl2(P∩N)2]PF6 type salt

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Abstract

In the trinuclear, heterometallic cluster compound [Au2CuCl2(P∩N)2]PF6 metallophilic interactions give rise to very efficient cold-white light emission as a result of at least two thermally non-equilibrated emissive triplet states (one of mainly Cu → py and the other of Au → py character, respectively) with exceptional spin–orbit coupling and short emission lifetimes, which are competitive to PtII- and IrIII-based emitters.

Graphical abstract: Highly efficient cold-white light emission in a [Au2CuCl2(P∩N)2]PF6 type salt

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Publication details

The article was received on 16 Jan 2017, accepted on 09 Feb 2017 and first published on 09 Feb 2017


Article type: Communication
DOI: 10.1039/C7DT00180K
Dalton Trans., 2017,46, 3438-3442
  • Open access: Creative Commons BY license
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    Highly efficient cold-white light emission in a [Au2CuCl2(P∩N)2]PF6 type salt

    E. Hobbollahi, M. List, B. Hupp, F. Mohr, R. J. F. Berger, A. Steffen and U. Monkowius, Dalton Trans., 2017, 46, 3438
    DOI: 10.1039/C7DT00180K

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