Jump to main content
Jump to site search

Issue 9, 2017
Previous Article Next Article

Ring opening of a sterically crowded 1,2-oxaphosphetane complex

Author affiliations

Abstract

The first example of a ring opening reaction of a 1,2-oxaphosphetane complex is reported, i.e., water in the presence of [Li(12-crown-4)]Cl furnished a C–OH functional phosphinito complex. Employment of the latter in ring forming reactions with Me2ECL2 (E = Si, Ge) using different nitrogen bases is also described.

Graphical abstract: Ring opening of a sterically crowded 1,2-oxaphosphetane complex

Back to tab navigation

Supplementary files

Article information


Submitted
12 Jan 2017
Accepted
03 Feb 2017
First published
14 Feb 2017

Dalton Trans., 2017,46, 2904-2909
Article type
Paper

Ring opening of a sterically crowded 1,2-oxaphosphetane complex

A. W. Kyri, P. Brehm, G. Schnakenburg and R. Streubel, Dalton Trans., 2017, 46, 2904
DOI: 10.1039/C7DT00136C

Social activity

Search articles by author

Spotlight

Advertisements