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Issue 9, 2017
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Synthesis of hydroxyl-functionalized N-heterocyclic carbene gold(i) complexes and peptide conjugates

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Abstract

The synthesis and characterization of a series of new cationic gold(I) complexes with hydroxyl-functionalized N-heterocyclic carbene (NHC) ligands is described. They are valuable building blocks for further derivatization: as a first example, coupling with amino acids and a dipeptide, respectively, successfully results in amino acid and peptide conjugates that are hard to obtain by other synthetic routes.

Graphical abstract: Synthesis of hydroxyl-functionalized N-heterocyclic carbene gold(i) complexes and peptide conjugates

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Publication details

The article was received on 22 Dec 2016, accepted on 09 Feb 2017 and first published on 09 Feb 2017


Article type: Paper
DOI: 10.1039/C6DT04834J
Dalton Trans., 2017,46, 2988-2997

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    Synthesis of hydroxyl-functionalized N-heterocyclic carbene gold(I) complexes and peptide conjugates

    T. Diehl, M. T. S. Krause, S. Ueberlein, S. Becker, A. Trommer, G. Schnakenburg and M. Engeser, Dalton Trans., 2017, 46, 2988
    DOI: 10.1039/C6DT04834J

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