Issue 19, 2017

Ni(ii) complex on a bispyridine-based porous organic polymer as a heterogeneous catalyst for ethylene oligomerization

Abstract

A Ni(II) catalyst incorporated into a new porous organic polymer, Ni(II)-POP-1, is prepared via a click reaction followed by metalation with NiCl2. It shows good catalytic activity for liquid-phase ethylene dimerization in the presence of Et2AlCl as a co-catalyst, generating 1-butene.

Graphical abstract: Ni(ii) complex on a bispyridine-based porous organic polymer as a heterogeneous catalyst for ethylene oligomerization

Supplementary files

Article information

Article type
Communication
Submitted
26 Jun 2017
Accepted
31 Aug 2017
First published
04 Sep 2017

Catal. Sci. Technol., 2017,7, 4351-4354

Ni(II) complex on a bispyridine-based porous organic polymer as a heterogeneous catalyst for ethylene oligomerization

M. J. Kim, S. Ahn, J. Yi, J. T. Hupp, J. M. Notestein, O. K. Farha and S. J. Lee, Catal. Sci. Technol., 2017, 7, 4351 DOI: 10.1039/C7CY01274H

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