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Issue 36, 2017
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Probing RbBr solvation in freestanding sub-2 nm water clusters

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Abstract

Concentration dependent solvation of RbBr in freestanding sub-2 nm water clusters was studied using core level photoelectron spectroscopy with synchrotron radiation. Spectral features recorded from dilute to saturated clusters indicate that either solvent shared or contact ion pairs are present in increasing amount when the concentration exceeds 2 mol kg−1. For comparison, spectra from anhydrous RbBr clusters are also presented.

Graphical abstract: Probing RbBr solvation in freestanding sub-2 nm water clusters

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Supplementary files

Article information


Submitted
30 Jun 2017
Accepted
01 Sep 2017
First published
04 Sep 2017

Phys. Chem. Chem. Phys., 2017,19, 25158-25167
Article type
Paper

Probing RbBr solvation in freestanding sub-2 nm water clusters

L. Hautala, K. Jänkälä, M. Mikkelä, P. Turunen, N. L. Prisle, M. Patanen, M. Tchaplyguine and M. Huttula, Phys. Chem. Chem. Phys., 2017, 19, 25158
DOI: 10.1039/C7CP04398H

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