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Issue 32, 2017
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X-ray spectroscopy on the active ion in laser crystals

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Abstract

The active ions in typical laser crystals were studied with Resonant Inelastic X-ray Scattering (RIXS) and Partial Fluorescence Yield X-ray Absorption (PFY-XAS) spectroscopies as solid state model systems for dilute active centers. We analyzed Ti3+ and Cr3+ in α-Al2O3:Ti3+ and LiCaAlF6:Cr3+, respectively. The comparison of experimental data with semi-empirical multiplet calculations provides insights into the electronic structure and shows how measured crystal field energies are related across different spectroscopies.

Graphical abstract: X-ray spectroscopy on the active ion in laser crystals

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Article information


Submitted
08 May 2017
Accepted
26 Jul 2017
First published
26 Jul 2017

Phys. Chem. Chem. Phys., 2017,19, 21800-21806
Article type
Paper

X-ray spectroscopy on the active ion in laser crystals

P. S. Miedema, R. Mitzner, S. Ganschow, A. Föhlisch and M. Beye, Phys. Chem. Chem. Phys., 2017, 19, 21800 DOI: 10.1039/C7CP03026F

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