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Issue 70, 2017
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Iodoarene-catalyzed oxidative transformations using molecular oxygen

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Abstract

Molecular oxygen serves as a useful oxidant for the glycol scission of 1,2-diols and the Hofmann rearrangement of primary amides using pentamethyliodobenzene as a catalyst. The use of isobutyraldehyde and Lewis basic nitriles under O2 enabled the iodine(I)/(III) catalytic cycle, where in situ-generated peracid acts as a terminal oxidant.

Graphical abstract: Iodoarene-catalyzed oxidative transformations using molecular oxygen

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Article information


Submitted
05 Jul 2017
Accepted
08 Aug 2017
First published
08 Aug 2017

Chem. Commun., 2017,53, 9781-9784
Article type
Communication

Iodoarene-catalyzed oxidative transformations using molecular oxygen

K. Miyamoto, J. Yamashita, S. Narita, Y. Sakai, K. Hirano, T. Saito, C. Wang, M. Ochiai and M. Uchiyama, Chem. Commun., 2017, 53, 9781
DOI: 10.1039/C7CC05160C

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