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Issue 41, 2017
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Access to cyclic gem-difluoroacyl scaffolds via electrochemical and visible light photocatalytic radical tandem cyclization of heteroaryl chlorodifluoromethyl ketones

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Abstract

A variety of unprecedented scaffolds containing a difluoroacyl moiety were obtained in moderate to good yields, with excellent diastereoselectivity, via electrochemical or photochemical activation of difluoroacyl heteroaryles with a series of olefinic substrates.

Graphical abstract: Access to cyclic gem-difluoroacyl scaffolds via electrochemical and visible light photocatalytic radical tandem cyclization of heteroaryl chlorodifluoromethyl ketones

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Article information


Submitted
18 Apr 2017
Accepted
02 May 2017
First published
02 May 2017

Chem. Commun., 2017,53, 5653-5656
Article type
Communication

Access to cyclic gem-difluoroacyl scaffolds via electrochemical and visible light photocatalytic radical tandem cyclization of heteroaryl chlorodifluoromethyl ketones

C. Adouama, R. Keyrouz, G. Pilet, C. Monnereau, D. Gueyrard, T. Noël and M. Médebielle, Chem. Commun., 2017, 53, 5653
DOI: 10.1039/C7CC02979A

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