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Issue 45, 2017
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Coupling between the photo-excited cyclic π system and the 4f electronic system in a lanthanide single molecule magnet

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Abstract

A new type of electronic interaction which couples two angular momenta, i.e. the angular momentum of a localized 4f system (J) and an orbital angular momentum generated in a cyclic π conjugated system by irradiation with a circularly-polarized light, has been identified in a lanthanide single molecule magnet.

Graphical abstract: Coupling between the photo-excited cyclic π system and the 4f electronic system in a lanthanide single molecule magnet

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Publication details

The article was received on 18 Apr 2017, accepted on 12 May 2017 and first published on 23 May 2017


Article type: Communication
DOI: 10.1039/C7CC02960H
Chem. Commun., 2017,53, 6168-6171

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    Coupling between the photo-excited cyclic π system and the 4f electronic system in a lanthanide single molecule magnet

    K. Kizaki, H. Ozawa, T. Kobayashi, R. Matsuoka, Y. Sakaguchi, A. Fuyuhiro, T. Fukuda and N. Ishikawa, Chem. Commun., 2017, 53, 6168
    DOI: 10.1039/C7CC02960H

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