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Issue 36, 2017
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Rhodium-catalyzed addition of sulfonyl hydrazides to allenes: regioselective synthesis of branched allylic sulfones

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Abstract

A rhodium-catalyzed regioselective addition of sulfonyl hydrazides to allenes is reported. With Rh(I)/DPEphos/benzoic acid as the catalyst system, branched allylic sulfones can be obtained, in good to excellent yields and regioselectivities.

Graphical abstract: Rhodium-catalyzed addition of sulfonyl hydrazides to allenes: regioselective synthesis of branched allylic sulfones

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Supplementary files

Article information


Submitted
28 Mar 2017
Accepted
07 Apr 2017
First published
07 Apr 2017

Chem. Commun., 2017,53, 4966-4968
Article type
Communication

Rhodium-catalyzed addition of sulfonyl hydrazides to allenes: regioselective synthesis of branched allylic sulfones

V. Khakyzadeh, Y. Wang and B. Breit, Chem. Commun., 2017, 53, 4966
DOI: 10.1039/C7CC02375H

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