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Issue 33, 2017
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Visible-light-mediated radical insertion/cyclization cascade reaction: synthesis of phenanthridines and isoquinolines from isocyanides

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Abstract

A visible-light promoted single electron oxidation of ether enabled by photoredox catalysis has been accomplished. This procedure initiates a novel radical insertion/cyclization cascade reaction to generate phenanthridines and isoquinolines from easily available isocyanides under mild reaction conditions.

Graphical abstract: Visible-light-mediated radical insertion/cyclization cascade reaction: synthesis of phenanthridines and isoquinolines from isocyanides

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Publication details

The article was received on 09 Mar 2017, accepted on 31 Mar 2017 and first published on 31 Mar 2017


Article type: Communication
DOI: 10.1039/C7CC01813D
Chem. Commun., 2017,53, 4585-4588

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    Visible-light-mediated radical insertion/cyclization cascade reaction: synthesis of phenanthridines and isoquinolines from isocyanides

    S. Feng, T. Li, C. Du, P. Chen, D. Song, J. Li, X. Xie and X. She, Chem. Commun., 2017, 53, 4585
    DOI: 10.1039/C7CC01813D

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