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Issue 34, 2017
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Supramolecular architectures self-assembled using long chain alkylated spin crossover cobalt(ii) compounds

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Abstract

Self-assembled hybrid supramolecular architectures formed between amphiphilic anions and long alkylated cationic cobalt(II) complexes of type [Co(Cn-terpy)2](C12-Glu)2 (n = 15–20) have been synthesized and characterized by TEM, PXRD and magnetic susceptibility measurements. The hybrids display wire or rolled sheet supramolecular arrangements with odd and even alkyl chain dependence, with the cobalt(II) centres exhibiting gradual spin-crossover behaviours.

Graphical abstract: Supramolecular architectures self-assembled using long chain alkylated spin crossover cobalt(ii) compounds

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Article information


Submitted
28 Feb 2017
Accepted
27 Mar 2017
First published
28 Mar 2017

Chem. Commun., 2017,53, 4685-4687
Article type
Communication

Supramolecular architectures self-assembled using long chain alkylated spin crossover cobalt(II) compounds

R. Akiyoshi, K. Kuroiwa, S. Alao Amolegbe, M. Nakaya, R. Ohtani, M. Nakamura, L. F. Lindoy and S. Hayami, Chem. Commun., 2017, 53, 4685
DOI: 10.1039/C7CC01501A

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