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Issue 10, 2017
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Postsynthetic N-methylation making a metal–organic framework responsive to alkylamines

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Abstract

The postsynthetically created electron-deficient 2,2′-bipyridinium moieties in a Zr-MOF provide charge-transfer interacting sites for recognizing and capturing alkylamines with excellent selectivity; meanwhile the MOF shows fast and reversible vapochromism and luminescence quenching in response to alkyamines.

Graphical abstract: Postsynthetic N-methylation making a metal–organic framework responsive to alkylamines

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Publication details

The article was received on 28 Dec 2016, accepted on 12 Jan 2017 and first published on 13 Jan 2017


Article type: Communication
DOI: 10.1039/C6CC10278F
Chem. Commun., 2017,53, 1747-1750

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    Postsynthetic N-methylation making a metal–organic framework responsive to alkylamines

    N. Yang, W. Sun, F. Xi, Q. Sui, L. Chen and E. Gao, Chem. Commun., 2017, 53, 1747
    DOI: 10.1039/C6CC10278F

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