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Issue 16, 2017
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Silver(I)-promoted insertion into X–H (X = Si, Sn, and Ge) bonds with N-nosylhydrazones

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Abstract

Silver(I)-promoted carbene insertion into X–H (X = Si, Sn, and Ge) bonds has been realized by using unstable diazo compounds, which are generated in situ from N-nosylhydrazones as carbene precursors. The reaction tolerates a wide range of functional groups and delivers a number of valuable silicon-containing compounds in very high yields (up to 96%). Moreover, organostannanes and organogermanes were as well effectively obtained in very good yields under optimal conditions.

Graphical abstract: Silver(i)-promoted insertion into X–H (X = Si, Sn, and Ge) bonds with N-nosylhydrazones

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Publication details

The article was received on 05 Dec 2016, accepted on 02 Feb 2017 and first published on 10 Feb 2017


Article type: Communication
DOI: 10.1039/C6CC09650F
Chem. Commun., 2017,53, 2503-2506

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    Silver(I)-promoted insertion into X–H (X = Si, Sn, and Ge) bonds with N-nosylhydrazones

    Z. Liu, Q. Li, Y. Yang and X. Bi, Chem. Commun., 2017, 53, 2503
    DOI: 10.1039/C6CC09650F

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