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Issue 5, 2017
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Synthesis and initial transition metal chemistry of the first PGeP pincer-type germylene

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Abstract

A PGeP pincer-type germylene, Ge(NCH2PtBu2)2C6H4, which contains two phosphane groups hanging from the N atoms of an N-heterocyclic germylene fragment, has been isolated for the first time. This compound has already furnished a rich transition metal derivative chemistry (Co, Rh, and Pd) that includes complexes containing bridging P,Ge,P-, chelating P,Ge- and pincer P,Ge,P-ligands.

Graphical abstract: Synthesis and initial transition metal chemistry of the first PGeP pincer-type germylene

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Article information


Submitted
21 Nov 2016
Accepted
14 Dec 2016
First published
14 Dec 2016

Chem. Commun., 2017,53, 893-896
Article type
Communication

Synthesis and initial transition metal chemistry of the first PGeP pincer-type germylene

L. Álvarez-Rodríguez, J. Brugos, J. A. Cabeza, P. García-Álvarez, E. Pérez-Carreño and D. Polo, Chem. Commun., 2017, 53, 893
DOI: 10.1039/C6CC09283G

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