Issue 28, 2017

1,2-Difunctionalization-type (hetero)arylation of unactivated alkenes triggered by radical addition/remote (hetero)aryl migration

Abstract

A novel difunctionalization-type (hetero)arylation of unactivated alkenes has been developed via remote 1,4(5)-(hetero)aryl migration triggered by radical alkene azidation, trifluoromethylation, or phosphonylation. The overall process serves as an unusual and reliable approach for straightforward access to diversely substituted ketones with broad functional group compatibility from readily available substrates and reagents.

Graphical abstract: 1,2-Difunctionalization-type (hetero)arylation of unactivated alkenes triggered by radical addition/remote (hetero)aryl migration

Supplementary files

Article information

Article type
Communication
Submitted
18 Nov 2016
Accepted
13 Mar 2017
First published
15 Mar 2017

Chem. Commun., 2017,53, 4038-4041

1,2-Difunctionalization-type (hetero)arylation of unactivated alkenes triggered by radical addition/remote (hetero)aryl migration

L. Li, Q. Gu, N. Wang, P. Song, Z. Li, X. Li, F. Wang and X. Liu, Chem. Commun., 2017, 53, 4038 DOI: 10.1039/C6CC09215B

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