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Issue 48, 2016
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Drastic solid-state luminescence color tuning of an archetypal Ir(III) complex using polyoxometalates and its application as a vapoluminescence chemosensor

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Abstract

Using a straightforward one-step synthetic procedure, the solid-state phosphorescence of the archetypal [IrIII(ppy)2(bpy)]+ complex has been successfully tuned from green to yellow, orange and red by its association with a series of polyoxometalates. Such new materials can exhibit remarkable vapoluminescence properties for the detection of volatile organic compounds (VOCs) even in the presence of moisture via a new polymorphous conversion mechanism.

Graphical abstract: Drastic solid-state luminescence color tuning of an archetypal Ir(iii) complex using polyoxometalates and its application as a vapoluminescence chemosensor

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Publication details

The article was received on 07 Oct 2016, accepted on 17 Nov 2016 and first published on 17 Nov 2016


Article type: Communication
DOI: 10.1039/C6TC04341K
J. Mater. Chem. C, 2016,4, 11392-11395

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    Drastic solid-state luminescence color tuning of an archetypal Ir(III) complex using polyoxometalates and its application as a vapoluminescence chemosensor

    P. Bolle, H. Serier-Brault, R. Génois, E. Faulques, A. Boulmier, O. Oms, M. Lepeltier, J. Marrot, A. Dolbecq, P. Mialane and R. Dessapt, J. Mater. Chem. C, 2016, 4, 11392
    DOI: 10.1039/C6TC04341K

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