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Issue 35, 2016
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Energy transfer in pendant perylene diimide copolymers

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Abstract

We report the synthesis, characterisation and polymerisation of two novel asymmetric perylene diimide acrylate monomers. The novel monomers form a sensitiser–acceptor pair capable of undergoing Förster resonance energy transfer, and were incorporated as copolymers with tert-butyl acrylate. The tert-butyl acrylate units act as spacers along the polymer chain allowing high concentrations of dye while mitigating aggregate quenching, leading to persistent fluorescence in the solid state at high concentrations of up to 0.3 M. Analysis of fluorescence kinetics showed efficient energy transfer between the optically dense sensitiser and the lower concentration acceptor luminophores within the polymer. This reduced reabsorption within the material demonstrates that the copolymer-scaffold energy transfer system has potential for use in luminescent solar concentrators.

Graphical abstract: Energy transfer in pendant perylene diimide copolymers

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Supplementary files

Article information


Submitted
22 Jun 2016
Accepted
10 Aug 2016
First published
12 Aug 2016

J. Mater. Chem. C, 2016,4, 8270-8275
Article type
Paper

Energy transfer in pendant perylene diimide copolymers

N. J. L. K. Davis, R. W. MacQueen, D. A. Roberts, A. Danos, S. Dehn, S. Perrier and T. W. Schmidt, J. Mater. Chem. C, 2016, 4, 8270
DOI: 10.1039/C6TC02555B

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