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Neutral-state black diketopyrrolopyrrole (DPP)-based conjugated polymers with the colour channels a* from −3 to 0 and b* from −2 to −7 are achieved by incorporating an additional donor segment – dialkoxythiophene (DalkOT), which leads to the enhancement in blue-wavelength absorption. The polymers display black-to-transmissive grey electrochromic switching with good redox stability.

Graphical abstract: Modulating high-energy visible light absorption to attain neutral-state black electrochromic polymers

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