Issue 36, 2016
From the journal:

Journal of Materials Chemistry B

A photobleaching resistant polymer supported hexanuclear molybdenum iodide cluster for photocatalytic oxygenations and photodynamic inactivation of Staphylococcus aureus†

Alicia Beltrán,a   Maxim Mikhailov,b   Maxim N. Sokolov,*bc   Vanesa Pérez-Laguna,d   Antonio Rezusta,d   María José Revillod  and  Francisco Galindo*a  

* Corresponding authors

a Universitat Jaume I, Departamento de Química Inorgánica y Orgánica, Avda. Sos Baynat s/n, Castellón, Spain
E-mail: francisco.galindo@uji.es

b Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Acad. Lavrentiev Prosp., 630090 Novosibirsk, Russia
E-mail: caesar@niic.nsc.ru

c Novosibirsk State University, 2 Ul. Pirogova, Novosibirsk, Russia

d Department of Microbiology – Miguel Servet University Hospital, Universidad de Zaragoza, IIS Aragón, Zaragoza, Spain

Abstract

The ability of a hexanuclear molybdenum cluster, [Mo6I8(CH3COO)6]2−, to carry out, upon irradiation, singlet oxygen mediated photocatalytic oxygenation reactions has been tested. This complex has been also supported on a solid polymeric matrix, yielding an immobilized photosensitizer with remarkable photostability and recyclability. Preliminary studies of antibacterial photoinactivation of Staphylococcus aureus have been conducted, with positive results.

Graphical abstract: A photobleaching resistant polymer supported hexanuclear molybdenum iodide cluster for photocatalytic oxygenations and photodynamic inactivation of Staphylococcus aureus

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Article information

DOI
https://doi.org/10.1039/C6TB01966H
Article type
Communication
Submitted
04 Aug 2016
Accepted
17 Aug 2016
First published
30 Aug 2016

J. Mater. Chem. B, 2016,4, 5975-5979

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A photobleaching resistant polymer supported hexanuclear molybdenum iodide cluster for photocatalytic oxygenations and photodynamic inactivation of Staphylococcus aureus

A. Beltrán, M. Mikhailov, M. N. Sokolov, V. Pérez-Laguna, A. Rezusta, M. J. Revillo and F. Galindo, J. Mater. Chem. B, 2016, 4, 5975 DOI: 10.1039/C6TB01966H

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