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Issue 48, 2016
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Room temperature-processed inverted organic solar cells using high working-pressure-sputtered ZnO films

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Abstract

This study reports improved performance of inverted organic solar cells by using high working-pressure sputtered ZnO. Sputtering produces highly crystalline ZnO without the need for thermal annealing. However, photovoltaic devices fabricated by using sputtered ZnO have shown lower power conversion efficiencies than those made by using sol–gel ZnO. On the other hand, sol–gel ZnO limits the flexible application of inverted organic solar cells because of high-temperature annealing. Therefore, a new method of sputtering under high working pressure is developed. The power conversion efficiency of inverted organic solar cells fabricated using this high working-pressure-sputtered ZnO (η = 8.6%, VOC = 0.77 V, JSC = 15.6 mA cm−2, and FF = 0.72) is superior to that of conventional sol–gel ZnO-based devices (η = 7.8%, VOC = 0.73 V, JSC = 16.0 mA cm−2, and FF = 0.63). Furthermore, utilizing the low temperature process of sputtering, flexible application is successfully achieved using polyethylene terephthalate indium tin oxide films.

Graphical abstract: Room temperature-processed inverted organic solar cells using high working-pressure-sputtered ZnO films

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Supplementary files

Article information


Submitted
18 Sep 2016
Accepted
07 Nov 2016
First published
09 Nov 2016

J. Mater. Chem. A, 2016,4, 18763-18768
Article type
Communication

Room temperature-processed inverted organic solar cells using high working-pressure-sputtered ZnO films

I. Jeon, Y. Qian, S. Nakao, D. Ogawa, R. Xiang, T. Inoue, S. Chiashi, T. Hasegawa, S. Maruyama and Y. Matsuo, J. Mater. Chem. A, 2016, 4, 18763
DOI: 10.1039/C6TA08068E

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