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Issue 8, 2016
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Luminescent metal complexes featuring photophysically innocent boron cluster ligands

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Abstract

We report the synthesis and characterization of a series of d8 metal complexes featuring robust and photophysically innocent strong-field chelating 1,1′-bis(o-carborane) (bc) ligand frameworks. A combination of UV-Vis spectroscopy, single crystal X-ray structural analysis, and DFT calculations of these species suggest that the dianionic bc ligand does not contribute to any visible metal-to-ligand charge transfer (MLCT) transitions, yet it provides a strong ligand field in these complexes. Furthermore, a bc-based Pt(II) complex containing a 4,4′-di-tert-butyl-2,2′-bipyridine ligand (dtb-bpy) has been prepared and was found to display blue phosphorescent emission dominated by MLCT from the Pt(II) center to the dtb-bpy ligand. Importantly, the bulky three-dimensional nature of the bc ligand precludes intermolecular Pt(II)⋯Pt(II) interactions in the solid state where the resulting compounds retain their emission properties. This study opens a potentially new avenue for designing organic light-emitting diode (OLED) materials with tunable properties featuring photophysically innocent boron-rich cluster ligands.

Graphical abstract: Luminescent metal complexes featuring photophysically innocent boron cluster ligands

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Publication details

The article was received on 24 Feb 2016, accepted on 18 Apr 2016 and first published on 27 Apr 2016


Article type: Edge Article
DOI: 10.1039/C6SC01146B
Citation: Chem. Sci., 2016,7, 5132-5138
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    Luminescent metal complexes featuring photophysically innocent boron cluster ligands

    K. O. Kirlikovali, J. C. Axtell, A. Gonzalez, A. C. Phung, S. I. Khan and A. M. Spokoyny, Chem. Sci., 2016, 7, 5132
    DOI: 10.1039/C6SC01146B

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