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Issue 3, 2016
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Halogenation of carbyne complexes: isolation of unsaturated metallaiodirenium ion and metallabromirenium ion

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Abstract

The halogenation of metallapentalyne led to the formation of metallapentalenes, which were fully characterized and studied by DFT calculations. The experimental and computational studies indicate that four resonance forms contribute to the overall structure of the metallapentalenes, and one resonance form could be viewed as the first examples of metallaiodirenium and metallabromirenium ions.

Graphical abstract: Halogenation of carbyne complexes: isolation of unsaturated metallaiodirenium ion and metallabromirenium ion

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Publication details

The article was received on 20 Oct 2015, accepted on 17 Nov 2015 and first published on 23 Nov 2015


Article type: Edge Article
DOI: 10.1039/C5SC03963K
Chem. Sci., 2016,7, 1815-1818
  • Open access: Creative Commons BY-NC license
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    Halogenation of carbyne complexes: isolation of unsaturated metallaiodirenium ion and metallabromirenium ion

    M. Luo, C. Zhu, L. Chen, H. Zhang and H. Xia, Chem. Sci., 2016, 7, 1815
    DOI: 10.1039/C5SC03963K

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