Issue 1, 2016

Cationic nickel porphyrinoids with unexpected reactivity

Abstract

Cationic nickel(II) complexes of two ring-contracted porphyrinoid ligands distantly related to the corrins were prepared by metal templated macrocyclisation. The compounds show reversible electron transfer processes and were found to be the first porphyrinoid-based catalysts for C–C cross-coupling.

Graphical abstract: Cationic nickel porphyrinoids with unexpected reactivity

Supplementary files

Article information

Article type
Edge Article
Submitted
26 Sep 2015
Accepted
13 Oct 2015
First published
16 Oct 2015
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY-NC license

Chem. Sci., 2016,7, 583-588

Author version available

Cationic nickel porphyrinoids with unexpected reactivity

R. Wicht, S. Bahnmüller, K. Brandhorst, P. Schweyen and M. Bröring, Chem. Sci., 2016, 7, 583 DOI: 10.1039/C5SC03663A

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