Issue 114, 2016

Surface modification and porosimetry of vertically aligned hexagonal mesoporous silica films

Abstract

Mesoporous silica films with vertically aligned hexagonal pores have been produced via the electrochemically assisted surfactant assembly (EASA) method using cetyltrimethylammonium bromide (CTAB) surfactant. Mesoporous silica powder has also been synthesised using the same surfactant. The pore walls of the silica powder and films have been grafted with organosilane reagents. The size of the pore, degree of grafting and effect on the properties of the pore have been investigated using porosimetry, contact angle, NMR and CHN analysis. The degree of grafting was found to be dependent upon the size of the grafting agent, with the smallest steric bulk grafting most effectively. It was found that the grafting of the pores with Me3SiCl greatly increased the hydrophobicity of the pore and reduced water penetration. Grafting with larger groups caused the film surface to be hydrophobic but had little effect on the penetration of water into the pores.

Graphical abstract: Surface modification and porosimetry of vertically aligned hexagonal mesoporous silica films

Supplementary files

Article information

Article type
Paper
Submitted
15 Sep 2016
Accepted
31 Oct 2016
First published
11 Nov 2016
This article is Open Access
Creative Commons BY license

RSC Adv., 2016,6, 113432-113441

Surface modification and porosimetry of vertically aligned hexagonal mesoporous silica films

C. Robertson, Andrew W. Lodge, P. Basa, M. Carravetta, A. L. Hector, R. J. Kashtiban, J. Sloan, D. C. Smith, J. Spencer and A. Walcarius, RSC Adv., 2016, 6, 113432 DOI: 10.1039/C6RA23059H

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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