Structure-induced catalysis enhancement of Cu-amino catalysts for rapidly selective oxidation of sulfides in the presence of H2O2

Zhi-Hui Zhang; Xu-Sheng Yang; Qing-Qing Zhang; Liang Wang; Ming-Yang He; Qun Chen; Xian-Feng Huang

doi:10.1039/C6RA22393A

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Structure-induced catalysis enhancement of Cu-amino catalysts for rapidly selective oxidation of sulfides in the presence of H₂O₂†

Zhi-Hui Zhang,

^a Xu-Sheng Yang,^a Qing-Qing Zhang,^a Liang Wang,^a Ming-Yang He,^a Qun Chen*^a and Xian-Feng Huang*^ab

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* Corresponding authors

^a Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, Changzhou University, Changzhou 213164, P. R. China
E-mail: huangxf@cczu.edu.cn, chenqunjpu@yahoo.com
Fax: +86-519-86330251
Tel: +86-519-86330251

^b School of Pharmaceutical Engineering & Life Science, Changzhou University, Changzhou 213164, P. R. China

Abstract

With benzyl phenyl sulfide as a model substrate and H₂O₂ as an oxidant, high selectivity toward the desired sulfoxide is obtained when using two Cu^II-amino acid complexes as catalysts, while strong stereospecific obstruction in a 1D helical array of complex 2 enables speedy sulfoxidation with excellent conversion.

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Article information

DOI: https://doi.org/10.1039/C6RA22393A
Article type: Communication
Submitted: 07 Sep 2016
Accepted: 17 Oct 2016
First published: 18 Oct 2016

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RSC Adv., 2016,6, 104036-104040

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Structure-induced catalysis enhancement of Cu-amino catalysts for rapidly selective oxidation of sulfides in the presence of H₂O₂

Z. Zhang, X. Yang, Q. Zhang, L. Wang, M. He, Q. Chen and X. Huang, RSC Adv., 2016, 6, 104036 DOI: 10.1039/C6RA22393A

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