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Issue 99, 2016, Issue in Progress
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Sulfoximinocarbonylation of aryl halides using heterogeneous Pd/C catalyst

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Abstract

A three component protocol has been developed for the synthesis of N-aroyl sulfoximines by the carbonylation of aryl halides followed by nucleophilic attack of NH-sulfoximines. This reaction tolerates a range of aryl iodides and sulfoximines to provide the N-aroyl sulfoximines in good to excellent yields. Less reactive aryl bromides also underwent sulfoximinocarbonylation and afforded the products. This methodology is free from phosphine ligands. The heterogeneous Pd/C catalyst was successfully recovered and reused for up to five consecutive catalytic cycles.

Graphical abstract: Sulfoximinocarbonylation of aryl halides using heterogeneous Pd/C catalyst

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Supplementary files

Article information


Submitted
30 Aug 2016
Accepted
28 Sep 2016
First published
28 Sep 2016

RSC Adv., 2016,6, 97152-97159
Article type
Paper

Sulfoximinocarbonylation of aryl halides using heterogeneous Pd/C catalyst

B. D. Bala, N. Sharma and G. Sekar, RSC Adv., 2016, 6, 97152
DOI: 10.1039/C6RA21732J

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