Issue 84, 2016

B(C6F5)3 catalysed 1,6-conjugate allylation of para-quinone methides: expedient access to allyl diarylmethanes

Abstract

An effective method for the synthesis of unsymmetrical allyldiaryl methanes is portrayed. This protocol involves a Lewis acid catalysed 1,6-conjugate addition of allyltrimethyl silanes to para-quinone methides, which enabled us to synthesize a variety of unsymmetrical allyl diarylmethanes in good to excellent yields in a very short reaction period.

Graphical abstract: B(C6F5)3 catalysed 1,6-conjugate allylation of para-quinone methides: expedient access to allyl diarylmethanes

Supplementary files

Article information

Article type
Communication
Submitted
27 Jul 2016
Accepted
19 Aug 2016
First published
19 Aug 2016

RSC Adv., 2016,6, 80718-80722

B(C6F5)3 catalysed 1,6-conjugate allylation of para-quinone methides: expedient access to allyl diarylmethanes

S. Mahesh, G. Kant and R. V. Anand, RSC Adv., 2016, 6, 80718 DOI: 10.1039/C6RA19069C

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