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The development of oxa-hetero-Diels–Alder reactions of enones with aryl trifluoromethyl ketones to afford tetrahydropyranones bearing trifluoromethyl-substituted tetrasubstituted carbon centers is reported. The reactions were catalyzed by an amine-based catalyst system and afforded the products with er values up to 97 : 3.

Graphical abstract: Catalytic enantioselective oxa-hetero-Diels–Alder reactions of enones with aryl trifluoromethyl ketones

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