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Issue 43, 2016
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Palladium nanoparticles catalyzed aroylation of NH-sulfoximines with aryl iodides

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Abstract

A novel approach towards aroylation of NH-sulfoximines using Pd nanoparticles stabilized by a binaphthyl backbone (Pd-BNP) has been developed. This synthetic protocol involves the Pd-BNP promoted carbon monoxide insertion of aryl iodides to form an aroyl intermediate which further reacts with NH-sulfoximines to form N-aroyl sulfoximine derivatives in good to excellent yields. The Pd-BNP catalyst was recovered and reused up to six times.

Graphical abstract: Palladium nanoparticles catalyzed aroylation of NH-sulfoximines with aryl iodides

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Supplementary files

Article information


Submitted
29 Feb 2016
Accepted
02 Apr 2016
First published
14 Apr 2016

RSC Adv., 2016,6, 37226-37235
Article type
Paper

Palladium nanoparticles catalyzed aroylation of NH-sulfoximines with aryl iodides

N. Sharma and G. Sekar, RSC Adv., 2016, 6, 37226
DOI: 10.1039/C6RA05334C

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