1H-Azadienes were synthesized from allyl azides by ruthenium catalysis under mild and neutral conditions. Applications of the 1H-azadienes were demonstrated for the one-pot synthesis of N-benzyl-1-azadienes, hydrazones, tertiary carbinamines, dieneamide, and N-cyclohexenylacetamides. Two 1H-azatrienes were also synthesized, which were transformed to pyridine derivatives.
Y. Kwon, M. Jeon, J. Y. Park, Y. H. Rhee and J. Park, RSC Adv., 2016, 6, 661 DOI: 10.1039/C5RA26230E
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