Jump to main content
Jump to site search

Issue 26, 2016
Previous Article Next Article

Efficient removal of rhodamine 6G dye from aqueous solution using nickel sulphide incorporated polyacrylamide grafted gum karaya bionanocomposite hydrogel

Author affiliations

Abstract

This research paper reports the synthesis and usage of the polyacrylamide (PAAm) grafted gum karaya (Gk) and nickel sulphide nanoparticle based hydrogel to effectively remove rhodamine 6G dye (R6G) from aqueous solution. Initially, the hydrogel polymer of the Gk with the PAAm was synthesized using the graft co-polymerization technique. In the second step, the nickel sulphide nanoparticles were incorporated in situ within the hydrogel polymer matrix. The synthesized hydrogel nanocomposite was characterized using different characterization techniques such as XRD, FTIR, SEM, and TEM. The changes in the surface area, pore volume and pore diameter after the incorporation of nanoparticles were studied using the BET technique. The adsorption of R6G onto the hydrogel nanocomposite followed the Langmuir adsorption isotherm with a maximum adsorption capacity of 1244.71 mg g−1. The adsorption kinetics followed the pseudo-second order rate model. Furthermore, various thermodynamic parameters such as ΔS°, ΔH° and ΔG° were calculated to check the spontaneity and nature of the process of adsorption. The hydrogel nanocomposite was used for five successive cycles of adsorption–desorption. Therefore, the nanocomposite hydrogels have proved their potential for the removal of cationic dyes from aqueous solutions.

Graphical abstract: Efficient removal of rhodamine 6G dye from aqueous solution using nickel sulphide incorporated polyacrylamide grafted gum karaya bionanocomposite hydrogel

Back to tab navigation

Supplementary files

Article information


Submitted
17 Nov 2015
Accepted
09 Feb 2016
First published
09 Feb 2016

RSC Adv., 2016,6, 21929-21939
Article type
Paper

Efficient removal of rhodamine 6G dye from aqueous solution using nickel sulphide incorporated polyacrylamide grafted gum karaya bionanocomposite hydrogel

N. Kumar, H. Mittal, V. Parashar, S. S. Ray and J. C. Ngila, RSC Adv., 2016, 6, 21929
DOI: 10.1039/C5RA24299A

Social activity

Search articles by author

Spotlight

Advertisements