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Issue 9, 2016
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Hyperbranched supramolecular polymer constructed from twisted cucurbit[14]uril and porphyrin via host–guest interactions

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Abstract

A novel supramolecular polymer Q[14]-TBPyP was successfully constructed from a host twisted cucurbit[14] (Q[14]) molecule and a four-arm 5,10,15,20-tetrakis(N-butyl-4-pyridinium)porphyrin tetrabromide (TBPyP) guest molecule depending on the host–guest interactions and characterized by NMR, ITC, DLS, electronic absorption, and fluorescence spectroscopy, representing the first cucurbit[14]uril-involved host–guest supramolecular polymer.

Graphical abstract: Hyperbranched supramolecular polymer constructed from twisted cucurbit[14]uril and porphyrin via host–guest interactions

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Supplementary files

Article information


Submitted
28 Jun 2016
Accepted
20 Jul 2016
First published
21 Jul 2016

Org. Chem. Front., 2016,3, 1144-1148
Article type
Research Article

Hyperbranched supramolecular polymer constructed from twisted cucurbit[14]uril and porphyrin via host–guest interactions

Z. Gao, J. Zhang, N. Sun, Y. Huang, Z. Tao, X. Xiao and J. Jiang, Org. Chem. Front., 2016, 3, 1144 DOI: 10.1039/C6QO00310A

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