Jump to main content
Jump to site search

Issue 8, 2016
Previous Article Next Article

Stimuli-responsive supramolecular gel constructed by pillar[5]arene-based pseudo[2]rotaxanes via orthogonal metal–ligand coordination and hydrogen bonding interaction

Author affiliations

Abstract

A pseudo[2]rotaxane formed from a dimethoxypillar[5]arene host and an amide-functionalized pyridine derivative guest was constructed in CHCl3, which could further assemble into a linear supramolecular polyrotaxane upon adding Pd(OAc)2via the incorporation of metal–ligand coordination. Furthermore, the obtained polyrotaxane could self-assemble to form a supramolecular gel at high concentration, which showed external stimuli-responsiveness.

Graphical abstract: Stimuli-responsive supramolecular gel constructed by pillar[5]arene-based pseudo[2]rotaxanes via orthogonal metal–ligand coordination and hydrogen bonding interaction

Back to tab navigation

Supplementary files

Article information


Submitted
12 May 2016
Accepted
31 May 2016
First published
01 Jun 2016

Org. Chem. Front., 2016,3, 966-970
Article type
Research Article

Stimuli-responsive supramolecular gel constructed by pillar[5]arene-based pseudo[2]rotaxanes via orthogonal metal–ligand coordination and hydrogen bonding interaction

X. Wu, Y. Yu, L. Gao, X. Hu and L. Wang, Org. Chem. Front., 2016, 3, 966
DOI: 10.1039/C6QO00197A

Social activity

Search articles by author

Spotlight

Advertisements