Issue 2, 2016

Glycosylation via remote activation of anomeric leaving groups: development of 2-(2-propylsulfinyl)benzyl glycosides as novel glycosyl donors

Abstract

2-(2-Propylsulfinyl)benzyl glycoside was designed as a new type of glycosyl donor which could be activated via remote mode. This glycosyl donor and its reduced form could act as active and latent donors respectively in a latent-active glycosylation strategy. Details of the discovery of this novel glycosyl donor are reported in this article.

Graphical abstract: Glycosylation via remote activation of anomeric leaving groups: development of 2-(2-propylsulfinyl)benzyl glycosides as novel glycosyl donors

Supplementary files

Article information

Article type
Research Article
Submitted
08 Nov 2015
Accepted
09 Dec 2015
First published
14 Dec 2015

Org. Chem. Front., 2016,3, 177-183

Author version available

Glycosylation via remote activation of anomeric leaving groups: development of 2-(2-propylsulfinyl)benzyl glycosides as novel glycosyl donors

P. Shu, W. Yao, X. Xiao, J. Sun, X. Zhao, Y. Zhao, Y. Xu, J. Tao, G. Yao, J. Zeng and Q. Wan, Org. Chem. Front., 2016, 3, 177 DOI: 10.1039/C5QO00359H

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