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Two asymmetric conjugated monomers of AB2-1 and AB2-2 with both dibenzo-24-crown-8 and dibenzylamine groups can self-assemble to form micellar and vesicular aggregates under acidic conditions, during which supramolecular hyperbranched polymers form controllably via host–guest recognition between dibenzo-24-crown-8 and dibenzylammonium groups.

Graphical abstract: Supramolecular polymerization induced self-assembly into micelle and vesicle via acid–base controlled formation of fluorescence responsive supramolecular hyperbranched polymers

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