Mildly basic aqueous conditions facilitated the tert-butyl peroxybenzoate (TBPB) mediated dehydrogenative addition of a range of ethers, including acetals, to diverse substituted 2-isocyanobiaryls. Mechanistic studies suggest that this radical cascade is an example of base promoted homolytic aromatic substitution (BHAS).
C. Anton-Torrecillas, D. Felipe-Blanco and J. C. Gonzalez-Gomez, Org. Biomol. Chem., 2016, 14, 10620 DOI: 10.1039/C6OB02103D
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